In this work the synthesis of Au-doped and Pt-doped TiO2 nanoparticles employing sol-gel methodology. The doping procedures based on chemical reduction and UV photodeposition.
The present work includes the synthesis of different Schiff’s bases [3(A-C)] by the reaction of 2-Aminopyridine [2] with benzaldehyde and its derivatives [1(A-C)]. These Schiff’s bases react with benzoyl chloride [4] to yield benzamide derivatives [5(A-C)]. The synthesis of L-amino acid derivatives [6(A-C)–10(A-C)] has been performed by the reaction of benzamide derivatives [5(A-C)] with (Glycine, L-Alanine, L-Phenylalanine, L-Asparatic acid and L-Asparagine).
This study involves the preparations of some pyridine derivatives starting from Isonicotinic acid (1) following these steps :First : The Synthesis of Isonicotinoyl acid chloride (2) by The reaction of Isonicotinic acid (1) and thionylchloride .Second : The Synthesis of some amide and ester derivatives by reaction between Isonicotinoyl acid chloride (2) and substituent amine or phenol derivatives ( Semicarbazide, Thiosemicarbazide, Benzohydrazide, Aniline, 4-phenylazoaniline, 4-phenylazophenol, p-Aminophenol, p-Aminoacetophenone, m-Toluidine, 4-Bromoaniline )
