M.Sc.

Synthesize and Characterization of Mn(II), Co(II),Fe(III) and Cu(II) complexes with substituted bis (oxadiazole sulfide).

1,3,4-Oxadiazole derivatives were prepared which have a number of therapeutic applications, and in a purpose of investigating the coordination behavior of new compounds towards transition metal ion, these compounds are prepared by oxidation of 5-aryl-1,3,4-oxadiazole-3-thiol using hydrogen peroxide forming bis(5-aryl-1,3,4-oxadiazole-2-yl) disulfide.The 1,3,4-oxadiazole compounds (LI, LII and LIII) have been used as ligands to prepared a number of transition metal complexes, which include [Fe(III), Co(II), Cu(II) and Mn(II)] ions.The ligands were characteriz

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SYNTHYESIS AND CHARACTERIZATION OF SOME TRANSITION METAL COMPLEXES WITH SCHIFF BASES DERIVED FROM 2-HYDRAZINO BENZOTHIAZOLE

The new ligands have been prepared in this work, which contain  benzothiazole linked to three different aldehydes throw imine group. these three ligands include:

LI=  2- (Acetlidine ) hydrazine benzothiazole.LII= 2- (O -hedroxy benzylidine) hydrazine benzothiazole. LIII=2-(2,4,6- trimethoxy benzylidine) hydrazine benzothiazole.

Which were reacted with the transition metal iones ( Ni(II) , Co(II) , Cu(II) , Cd(II) ).

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