HYDROCONVERSION OF N-HEXANE OVER PLATINUM SUPPORTED ZEOLITE CATALYSTS PREPARED BY SUPERCRITICAL TECHNIQUE
Two types of synthetic crystalline zeolites have been used as supports for noble-metal catalysts, namely HZSM-5 and H-Mordenite with SiO ratios of 90 and 40 respectively. The cations, Barium and Strontium zeolite forms were prepared by twice repeated ion-exchange with appropriate chloride solution of 3 normality at pH 7.2 and 50oC. The modified zeolites were dried at 110oC and calcined at 450o C by step wise temperature increase. The ion-exchange by strontium was more effective than by Barium cation. While the ability of H-replacement at HMOR was higher than in case of HZSM-5.